You have to consider two factors when you add a barrier to a room: the absorption of the barrier, and the diffraction of sound around the barrier. Both are a function of frequency.
Short answer: it's pretty easy to absorb high frequencies, and it's easy for a barrier to obstruct them using a reasonable size. As we start to consider lower frequencies, the barrier starts to not work as well. We have to compensate by using a larger, thicker barrier with better low-frequency absorption coefficients.
So the Reflexion-sized objects are fairly good at high-mids and up, not so good at lows. Of course, our hearing is most sensitive to noise in the presence range, where the barrier will work fairly well. Just keep in mind its lower frequency limit for effective use (probably ~500-1kHz for the Reflexion).
Also consider that these same frequencies are fairly well rejected by a cardioid microphone . . .