First there appears to be some confusion about dB SPL (which is used to measure Sound Pressure Levels, or the level your ears are hearing) and dBu (which is used to measure a voltage), which are not the same thing. The only thing you need to be concerned about is the voltage coming out of the SansAmp output, or dBu.
While I am reasonably sure that the level of the SansAmp output tracks the amp's "master" volume control (the direct outs on all of my amps do), that doesn't really mean anything other than you will get the largest dBu value (and the greatest dB SPL value) with the "master" volume turned to its loudest and the smallest dBu value (and the smallest db SPL value) with the "master" volume turned to its least value.
But, what are the actual values of the "largest dBu value" and the "smallest dBu value"? That's up to the amp manufacturer. I don't know why they would do it, but the amp manufacturer could set the "largest dBu value" to -60 dBu and the "smallest dBu value" to some value smaller than that, or they could set the "smallest dBu value" at +4 dBu and the "largest dBu value" at some value larger than that. And there's no guarantee that the dBu value exactly tracks the dB SPL value.
So, you really have to look at dB SPL and dBu as the two totally separate things they are.
Now...to the OP...
I would recommend that you not buy a pad or a mixer or anything other than the XLR-TRS balanced cable I recommended. The reasoning behind this is quite simple...you will only be buying one inexpensive item that will in all probability solve your problem.
And even if the cable by itself doesn't solve your problem, you're going to need it for any other solutions you might need to try.
Make the connections between the amp and the interface I described in my earlier post. Turn the SENS control for the input you are using on the Roland Duo-Capture Ex to its lowest level, and set your guitar amp to whatever level you wish to use. With Cakewalk (or whatever DAW you are using) running, hit a chord on the guitar and gradually turn up the SENS control until the input channel in Cakewalk shows somewhere between -15 dBFS and -18 dBFS.
If the input level to your Roland Duo-Capture Ex is still too high, then invest in a -20 dBu pad. You can probably find an XLR pad that you would plug into your SansAmp output with one end, then plug the XLR end of your XLR-TRS into the pad. If not, 1/4" versions are available in various connector configurations. You want to make sure you get a balanced pad, and if you need to get another cable to plug the pad into your Roland interface make sure it's a TRS balanced cable; you should not use an ordinary guitar cable.
But if you make the correct connections with your XLR-TRS balanced cable you probably will not need anything other than that cable.
And, on the subject of connections, do not plug anything other than a microphone cable into the XLR inputs on your Roland interface as the XLR and 1/4" jacks have different input level specs...