Personally, I would put Pinstripes on the Batter side (the side you hit) and Ambassadors on the resonant side. The reason I suggest the Pinstripes are because these are economy drums, and I've found that thin heads do not sound as good on economy drums, but with a pinstripe on top, you can get a decent sound out of them without too much overtone....and it's the overtones where you'll hear the real difference in the quality of more expensive shells.
The sizes of the drums are probably the standard 12", 13" & 16" Toms, with
a 22" Kick, and a snare.
The Pinstripes are a 2-play (two layers of plastic) head, so they will have less ring and more "thud".
One thing I would suggest getting is a DVD called "Trust Your Ears" by Jeff Ocheltree.... I didn't even know this thing was out until I recently got it. He was John Bonham's drum Techj - in fact, he was the very first Drum tech....prior to him, the were no people who specialized in being a Roadie just for drums. You'll learn a lot of things that will save you a ton of frustration. I got mine off of E-bay for $18 new.
12"
Pinstripe $12.28
Ambassador $10.58
13"
Pinstripe $12.58
Ambassador $10.88
14"
Pinstripe $13.08
Ambassador $10.58 (14" Snare-side head)
16"
Pinstripe $14.58
Ambassador $13.08
22"
Pinstripe $29.78
Ambassador $26.98
Now depending upon if you want a hole in the Resonant head of the Kick drum - you can either cut a hole yourself, or these days you can buy a head with the hole already cut in it.
I priced these heads from Interstate Music online
Here's the URL for the main Remo drumhead page.
http://www.interstatemusic.com/webapp/wcs/stores/servlet/CategoryDisplay
I suggest Remo, other's may suggest some other brands - I can't simply because I've never used them. To make a long story short, I use drums in sizes that companies like Evans only make certain models in these sizes - so I personally can't use these "newer" drumhead lines (like the Evans Genera series heads....aka G1 and G2.)
Just because I didn't suggest them, doesn't mean that they aren't worth looking into, I just don't have any experience with them.
I have used both Aquarian and Attack heads on my snare and was happy with both.
One other HEad I could suggest if you're after a more Hard Rock metal type of sound, is the Ludwig "Black Collar" heads - these are a clear head with a Black muffling collar on them - basically a second piece of drum head that helps cut out the overtones. I love Ludwig Strider heads as well, but they no longer make any of these heads in the Kick and Floor tom sizes that I use.
Tim