A 212 will not automatically be quieter - it is a matter of the impedance of the cabinet. Depending on the speakers inside, and how its wired, a 212 may actually be the same impedance as a 112, or a 412, or a couple of 412s. And yes, I've seen guys plug a 5 watt amp into a 412. If the impedance is the same, doubling the number of speakers will probably give you a little more volume, and will certainly give you a more low end. You just have to wire the speakers in such a way that they don't change the overall impedance load on the amp. Of course, there is a practical limit to that - at some point, the physics of it just don't work any more.
The problem comes in when the impedance is out of whack. Impedance is kind of like resistance, and if the impedance is too low the amp will try to push too much current through the speakers, which will make the wires in the output transformer overheat, and then they will die. Too much impedance, on the other hand, is not going to kill your amp, but will make it a bit quieter - not much, and possibly not enough for you to notice without a dB SPL meter, but a bit quieter - up to a point, of course, because eventually you can have problems. You don't want to plug an 2 ohm output into a 16 ohm speaker, but an 8 ohm output into a 16 ohm speaker (or group of speakers) is fine. Just don't go the other way. As a rule of thumb, doubling the speakers impedance won't damage anything. Any more than that isn't worth bothering with.
By the way, I've not actually heard the amp in question, so I don't know what it sounds like. Tube amps are not automatically great, just as solid state are not automatically bad (well, for clean sounds - the Roland Jazz Chorus is amazing, and the Polytone Mini-Brute is fantastic, but only for clean sounds). I'd want to try the thing before I spent any money on it, even if it is cheap.
Light
"Cowards can never be moral."
M.K. Gandhi