
dgatwood
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As you might see, there is confusion in nomenclature amongst musicians and engineers. This is because in engineering, "first order" is (usually) in reference to the fundamental, thus "second order" is 2x the fundamental frequency, etc. This corresponds to what a musician understands as the first harmonic, the octave.
To make things more confusing, your definition of "even order" differs from the mathematical definition. I hope you're just being sloppy. If not, then the engineering definitions are on crack.

Octaves are power-of-two harmonics, not even harmonics. Non-power-of-two even numbered harmonics are decidedly not octaves.
2^0 (1x) fundamental
2^1 (2x) octave up
3x octave and a fifth
2^2 (4x) two octaves up
5x two octaves and a third
6x two octaves and a fifth *
7x two octaves and a minor 7th
2^3 (8x) three octaves up
9x three octaves and a major second
10x three octaves and a major third *
11x three octaves and an augmented fourth (tritone)
12x three octaves and a fifth *
* indicates even numbered harmonic that is not an octave.
and so on.
Thirds and fifths are very close to being correct. It's the other intervals that are horrible. The even numbered harmonics get closer together the higher up the harmonic series you go. It should be noted that beyond 3x, the odd harmonics are way out of tune, which is one reason that they sound harsh. We're not talking a little bit like the fifths. The 5x harmonic is just a little flat, the 7x harmonic is very way flat, the 9x is just a hair sharp, the 11x is way flat (by almost a quarter step).
Another neat thing about the harmonics is that the error from ideal (in cents) for non-prime harmonics can be calculated by finding their prime factors and summing the errors of those harmonics. For example, the 3x harmonic is 2 cents sharp, the 5x harmonic is 14 cents flat, so the 15x harmonic is 12 cents flat.