The optical output of the card is labeled ADAT and the coaxial output is labeled S/PDIF. The coaxial is the sure bet since its S/PDIF signal is what a 2-channel DAT machine and the receiver should be able to receive, if the sample rate and bit depth are compatible. The optical ADAT output is expressly to send and 8-channel digital signal, but it's possible that you could configure it to carry an optical S/PDIF signal as well.
Devices like the DAT machine and the receiver "should" automatically sync directly from whatever digital input is selected. But if the signal is above 48kHz sample rate older devices might not recognize it.