I’d have to look at the whole gear assembly, but it’s possible the “gear C” experiences greater load, or lesser, so it was made out of different plastic, which unintentionally and unknowingly breaks down faster than the others…becomes brittle…something like that. It must just be a different plastic and likely by design. Or another possibility is, similar to what you are saying, if they didn’t make the gears in-house and outsourced them, which is not uncommon at all, the set of gears in your 464 may have come from different manufacturers OR different production runs and the formulation changed…this is highly possible because Teac may have ordered amounts for stock based on price-break quantities and then stock is depleted at different times for the different gears…so the gear set could be made up of gears manufactured at widely varying times and even from different manufacturers, and only time tells us of the ramifications. I think this is also why an old tape machine can have rubber components that are a mix of dried out, turned to goo, and still supple; different sources, different times for the parts all assembled on one machine.
I’ve encountered that tarnishing before on the gear spindle and IIRC I just made sure all the old grease and any other foreign material was cleaned off, polished it up as best I could with a piece of broken-in fine scotch-brite pad, and put it back together. I agree if it’s actually lost its plating, that is a really, really minor difference in the diameter of the spindle and I think that’s of no consequence here…clean it up, new grease, off we go.
Regarding tape type: I’m pretty certain, and my certainty is reinforced by the manual set, the 464, like other machines in the 400 series, is intended to use Cr02 tape only. Cassette machines that are designed for multiple tape types have manual or automatic switching that drives different bias levels and record EQ settings. The 464 doesn’t have any of that circuitry. According to the schematics the two switches are for 1. sensing a cassette is loaded and 2. record safety. That transport and/or the switch PCB may have been used in multiple different machines including Teac or Tascam consumer-format decks designed for multiple tape types. I could totally be wrong…I know there were a couple different versions of the 464 including one with an onboard BBE Sonic Maximizer circuit, and my manual set only covers what I think is the more common version.