This might be way off base.
But I'm sitting here trying to consider how you might scientifically approach the concept of accuracy in mic placement and selection.
I guess the ideal mic choice and placement would be indistinguishable from the actual instrument being played in the room, when played back on a full range, uncolored playback system.
So here's my thought.
You set up a measurement mic that's going to record everything you do.
This sucker's gonna be about five feet back (maybe closer, maybe further, just far enough that it's out of the near field - here I'm assuming that your experiments with position will be in the near field) and so recording (approximately) the sound of the instrument in the room.
You need an SPL meter at the same position as the mic.
You do your test recordings.
Record a short phrase, chords, whatever you want, with various mics and positions, each time keeping detailed records and making sure you keep your measurement mic files associated with your close mic files (I'd do it by just setting up two tracks for recording in whatever DAW, one is the experimental track, one is the control. The control always records what the measurement mic hears, the experimental gets the mics you are experimenting with. Most DAWs have facilities for making markers and notes and whatnot, so it shouldn't be too tough to keep it all arranged). You'll likely need help here, as you're gonna be using your SPL meter to measure and record (as accurately as possible) how loud the guitar in the room actually is.
Alright, now once you've done all your test recordings, you go find yourself the most accurate near field monitor you can find (my assumption up until now has been that you were doing this all in mono. If it's stereo placement you're working on, then you can probably figure out what would need adjusting).
You have your detailed records of the SPLs of your various takes at the measurement microphone, right?
You are gonna place the monitor as close as you can to the spot where the guitar was (I'd centralize it at the soundhole, though you might have a better idea where the sound projects from than I do) and use it to playback your experimental recordings.
Use the SPL meter to ensure that the playback through the monitor is as close as possible to how loud the actual guitar in the room was.
Now playback your experimental recordings and record them through the measurement mic again, this time on a third track.
Once this is done, you'll probably need to do a little bit of time aligning (due to latency introduced by the process of D/A conversion, sound transmission through the air then another round of A/D conversion) of this new measurement mic track with the original measurement mic tracks.
Now, if you play the original measurement mic tracks against the new ones, with the phase flipped on one of the tracks, there should be some significant frequency cancellation.
Your ideal mic in the ideal position would yield complete cancellation (though that's gonna be impossible), but whatever particular mic/position gets you closest to zero is gonna be the one that most closely/accurately matches the original source.
As I typed this, I thought of a million things that could introduce inconsistencies into the experiment.
I tried to keep it as simple as possible and introduce as few variables as possible.
Some things to keep in mind:
It's gonna be absolutely critical that the measurement mic and spl meter don't move at all throughout the duration of the test (and now that I think about it, you could probably skip the spl meter and just use your DAW's metering of the input from the measurement mic to perform the same function). Same goes for any furniture or other crap in the room. It might even be worth it for you (or your test guitar player) to sit in the same spot (as during the original recording) with the monitor in your (his/her) lap during the playback section of the testing, as I could see everything in the room affecting what the measurement mic hears.
It's gonna be mighty hard to capture the exact sound of the guitar in the room with just one mic in the near field.
This might mean either doing stereo recording or moving out of the nearfield for your experimental positions. Both of these options are gonna introduce more variables and inconsistencies.
I dunno. There's a lot more wrong here (probably most glaringly the fact that the experiment I just designed could be done by someone who is deaf - probably not ideal when you're dealing with sound) than there is right. But it's an idea and maybe a jumping off point.
Please let me know if you like it, have any thoughts, or just didn't understand anything I put in there.