do you think I will notice a huge difference in quality between 96 khZ and 192
No this will effect the sound frequecies that can be represented according to Nyquist theory
96K sampling Rate can represent up 48khz in sound frequency
192k sample rate can represent up to 96 khz in sound frequency
Human hearing generally maxes out between 16-20khz depending on age (ie babies might be able to go all the way to 22khz but hearing degrades a little every day), atmospheric pressure, humidity, how tired you are, how much coffe you've had, what kind of listening environment you are in, etc etc
Generally stated frequency range of many condenser mics 20 hz - 20 khz (considered human hearing range)
Frequency range of even really expensive monitors 40 hz - 30 khz but for "lower end" home recording stuff usually 45ish hz to 20 khz
so when you get to be worried about over 44.1k sample rate (Which can represent sound frequencies up to 22 khz (see a pattern yet?))you are worrying about sounds that:
1) your mics can't accurately record
2) your monitors can't accurately reproduce
3) your ears can't hear even if 1 and 2 were possible
If you want to test this, get a tone generator and start generating high frequency tones and see where your hearing craps out (assuming you have monitors that go to at least 20khz)
also from a computer DAW standpoint, each time you increase sample rate, you require exponentially more bandwidth to stream to disk, exponentially more disk space to store and exponentially more CPU power to process in both the DAW engine and with VST effects etc. so the higher the sample rate the faster your computer will run out of power to process and the sooner you will start having issues with stuttering, pops, cracks etc in recording and playback.
there is some argument that going above 44.1khz sample rate gives your software more room to hide artificats of processing in the inaudible "Nyquist Frequencies". Others argue that 44.1k sample can represent 22khz and give plenty of room above human hearing to hide processing artifacts. that's really up to you to decide if your selected DAW and plugins bring artifacts into hearing range.
There are other arguments about super high frequncy sound can be felt by the body/inner ear even if not heard but I would point to items 1 and 2 above and say, IMO even if that is true it's not particularly relevant because the mics don't capture the frequencies and the monitors dont reproduce them. But again it's up to you to pick which flavor of cool aid you wish to drink.
cheap APEX condenser mics
this will have more impact on quality than any sample rate concerns
