The human ear is not balanced at any sound preassure level. At 85dB, a 20Hz tone is percieved as only 20dB.
When playing a 50Hz tone at 85dB, you will percieve it as 70dB. That's 70/85=0.82... 82%
When playing a 50Hz tone at 65dB, you will percieve it as 40dB. 40/65=0.62. That's 62%.
If you like to risk permanent hearing damage like hearing loss, tinnitus or hyperacusis (over sensitivity) by being able to hear the 50Hz component of your mix 20 percent units louder, then that's your decision. (If your monitors even can reproduce those frequencies accurately anyway). It's no coincidence that something like 40% of everyone working with music has at least one of these conditions.
Many people feel unconfortable listening at 85dB (or even below). I got around a 80-85dB "unconfortable level" in a hearing test recently. Then where is the logic in that this would be the ear's "natural" listening level? A level that many people find unconfortable? Is it natural to be unconfortable? A more logical conclusion must be that the "natural" volume is where you feel perfectly confortable. And this is highly individual. (And so is most likely also the Fletcher-Munson graph).
If it turns out that you need a 6000W light bulb to be able to see the lowest frequency of the color spectrum, then this would of course be natures natural light level for the human eye!!!??? I hardly think so....
/Anders