To follow up with Chris's comment. Any note you strike on the guitar produces the fundemental note. So if you play say "A" which is 440Hz, then that note also produces integer multiple notes of 440. That is; 880, 1320, 1760 etc. But still the volume of 440 is the highest. And so you hear mostly 440 and a little bit of the other harmonics(880, 1320, 1760 etc).
Guitar players play harmonics in such a way that, the 440Hz is subdued. So, what happens is that you hear more of 880, 1320, 1760 etc and less of the 440. Hence the high screaming, yet melodious note of "A". This is what in general is knows as harmonics to musicians.
For "A", 880, 1320, 1760 etc., are referred to as Harmonics.
You can play natural harmonics by carefully placing your fingers over certain frets of the guitar. You can play artificial harmonics best with distortion ON and pinching the string between your finger and pick(If you did not know this yet).