Most likely, the way that wall is constructed is that it will have solid wood "headers" above the window, which should be at least as deep (top to bottom) in INCHES as the window is WIDE (in feet) - Sooo, 4' wide window, 4" header - 6' wide, 6" header, etc -
In order to get even SLIGHT isolation between wall surfaces at the window, you'd have to saw out at least 1/2" of wood all around the window frame to separate the two sides. Even if doing this were possible (it is, but you don't and shouldn't WANT to) you would STILL have the whole wall that was NOT separated, so even if you went with two glasses as thick as 3/8" and 1/2" and bedded them in neoprene, placing them as far apart as the wall thickness allowed, the rest of your wall construction would still limit the sound reduction between rooms to around STC 33.
If you want to keep the window, your best bet would be to check the classifieds for used/surplus building materials and see if you can find some bare, heavy, preferably laminated glass. You will probably have to have it custom cut to size, unless you get really lucky. It might be cheaper to re-size the window frame, but go carefully here unless you're SURE the wall is NOT LOAD BEARING.
Remove the window and any hardware, seal any holes with Fixall (paint supply area of Home Depot, etc) - install 3/4" square cleats all around the perimeter of the window casing, inset enough to allow room for neoprene "gaskets" inside, outside, and on the edges of each glass piece, with enough room left over outside each glass piece for the neoprene gasket and outer cleat. Caulk the glass all around each side before putting the outer neoprene and cleat on each side - use high grade silicone caulk at least.
With this narrow a space, you don't have enough depth to splay the glasses - be aware that you may get standing waves that will be centered somewhere near 1600 hZ - it may not happen, but if you see problems in that range the parallel glass could be the culprit.
If you can live without the glass, another alternative is building a window plug similar to this -
http://www.homer.com.au/phpBB2/viewtopic.php?t=239
The advantage to this is easy removal with little or no damage to the existing construction, should you move later... Steve