It's kind of a toss-up between two layers of 5/8 and one of each - there wouldn't be much of a mass change with only 10% more mass in that leaf of the wall, so I'd probably go with one layer of each. The difference in resonance might do as much for sound blocking as the slight extra mass, and the cost would be less.
The main thing when installing is not to overlook any details. Even one missed trick will lose you several dB of STC.
On the US Gypsum site (linked to in the previous links to John's site) most of these are mentioned, although some are easy to miss. They include using the proper screws, placing the bottom RC open side down to make fastening easier, keeping the bottom RC within 2" of the floor and the top RC within 6" of the ceiling, staggering screws between layers of wall-board, NOT using any screws thru wallboard over studs, NOT using construction adhesive to glue subsequent layers but instead letting each layer be semi-independent (just the screws) caulking EVERYTHING, taping the outer layer, running one layer horizontal and the other vertical, and probably a dozen other things I've forgotten to mention.
One thing I've not seen mentioned by anyone else, either because it's so obvious or ??? is to use masking tape or another temporary means to mark on adjacent surfaces exactly where the fastening surface of the RC is for each row, and on the other axis, exactly where the studs are - that way, when you get to the second layer, you'll know where NOT to put screws so they don't contact the studs or each other. If you use a 12" pattern per layer of wallboard, put a marker on the floor where you started so the second layer can be screwed 4" or 6" offset - keeping in mind that you still need to miss the studs...
USG also recommends that you run a heavy bead of caulk under both sides of runners (if steel) or plates (if wood), then a bead in top and bottom corners before the first layer, then fasten the second layer with about 1/4" gap from floor with spacers, then remove the spacers after attaching and run a bead of caulk in the gap.
Bottom line - if it won't float, it won't stop sound.
You didn't mention if the wall you're building has a double layer of wallboard on the completed side, but I hope so - insulation, unless you can get 2-3 lbs/cu ft density, won't make a lot of difference - that weight has been found to be the most effective for sound walls. Lighter and more bass gets through, heavier and more highs get through. For that weight, you need to find rockwool. Sometimes called mineral wool too. For that, check with commercial insulation contractors in your area. All places like Home Depot usually handle is the wimpy stuff, and some useless foam stuff.
Home Depot is reported to handle the RC-1, but a quick look last night in their drywall area turned up nada. I've not checked yet with my local Home Depot on the USG or Owens Corning Acoustic caulk - not holding too much hope though, probably a special order.
Can't think of anything else just now, hope some of this helped... Steve