No...The PCI Buss has more Bandwidth than the Firewire so there will be no Bottleneck.....
I believe you can run up to 6 FW Inputs on a single PCI slot and still not reach the full bandwidth of the PCI slot......
Even a simple PCI Video Capture card has enough bandwidth to transfer Uncompressed audio and Video to your PC without bottlenecking and uncompressed Video sucks up to 1.2gb of Data in a Single Minute and even 32 tracks of audio doesn"t even come close to 1.2gb per minute.....
Cheers