Definitely check out the sites that Light mentioned, especially AX84, for a first time builder. I'm about to start my first build from there. I've got a crap load of diy projects that I've been saying I'll get around to but it's time. I've been sitting on the diy tube amp idea for a few years now and it's making me sick that I have'nt started it yet. I sugguest reading up on basic electronics if you have'nt already. You should at least know how to read a schematic, how to identify components, and a basic understanding of how tube amps and there components work.
I've read about guys buying old tube pa's and radios and converting them into guitar amps but I don't see that being feasible if you have no clue of what to look for.
Also, a cool book I found is The Guitar Amp Handbook. A must read primer that does a really good job of explaining how all the components of an amp contribute to your overall sound. It covers components, the circuits that make up tube amps, speakers/cabs, basic maintenance, and a basic build of a low watt tube amp. There's alot of good info in this book for anyone looking to dial in on their own sound.