The sure fire way to wreck an ambient recording is to attempt to blend multiple mics. The spacing creates delays that produce weird comb filtering effects and although you can record m/s at the same time as X/Y or A/B or the other clever technique to separate tracks, pretty well you will end up settling on just one pair. It's a very personal choice and getting it wrong is easy. If the room sounds lovely, then I will perhaps go Blumlein, but if the room is smaller sounding then I like coincident pairs - lots don't but I prefer the results when listened to on loudspeakers.
As for the right place for the particular orchestra, if the space is unknown, then I will put on a pair of closed headphones -
DT100 or 150s in my case, and I set up my chosen mic pair on a tall stand, and while the orchestra are playing, I move it forwards and backwards and make changes in the height. Usually the 'right' place is over the conductors head, maybe 8-10ft above the ground. I tweak the up/down angle to cover the edges. The conductor adjusts the balance of the sections for his position, so being close to his position is best. What I'm looking for is individual instruments that are weak. Often the smaller orchestras are lacking in numbers for ones section but may have too many in others. If the piece has lots of solo instruments, that seem to fall into a black hole, this is the only time I will consider spot mics - but getting them to sit in the mix is very hard. It is level, pan, and time delay, and when you get it right, it sort of drops out as a separate instrument and just blurs in with the rest, but with it's own fader - which can be moved through a small range without producing any shift in the stereo field.
I find an X/Y scope plug in very handy - it really shows what is going on, and you can see the classic too mono/too stereo problems quite clearly. Stereo with two mics is harder than a multitrack session because just a few inches one way or the other make big differences, and many people forget up and down too. I always think adjusting position is far more important than faffing around with the clever techniques. Use these once your basic ears have got the simple techniques right. Many people add extra mics for room sound, and I've never found this actually works because of the horrible delays and sound field blurring it causes.
For me, the essential feature is two decent mics, a high stand, and a room where you can set up a couple of loudspeakers - PLUS - a system where you can talk back to the conductor. Video is useful, but not essential.
Start with X/Y or ORTF if you must, and learn how the adjustments sound. Ambient recording can be quite good fun, once you understand and are comfy with the basics. Stay away from spot mics until you really, really need them - because they are damn tricky to blend.
A few of my colleagues do half way house between multitrack close mic and a simple stereo system. They spread out the orchestra, and record each section in stereo - I never do it, but their recordings seem ok - but the stereo field, in my view is very poor.