I hate to repeat myself but I don't know what is this insane and ilogical freakness about ZIP files. Unless there is a inter-galactical-super-inteligent-new virus that came to life last night when I was sleeping I am not aware of NO ONE way that opening a zip file can infect someone computer. Any article, blog, site, etc, that says the contrary is just stuffing an irrational fear on people.
I am used to download tons of zip files from unknown sources and seriously I never (ever) got infect by no one of them. The same applies for other compacted formats such as rar, 7z, etc. Totally safe.
What happens is that some bad intention people may put an EXE file with a virus within a zip file. So the silly user go there, open the zip file and THEN double click the infected EXE file. OK, you opened the pandora box. But it wasn't the ZIP file that infected your computer, but the EXE file within that you double clicked.
You can open safely ANY zip (or any other compressed file) in your computer that absolutely nothing will happen. Now, if after to open it you see an EXE file there then it may be (or not) infected, but nothing will happen unless you DOUBLE click it. Yes, because DOUBLE clicking an EXE file you are executing it, and, therefore bringing the virus to life (if any). If you even SINGLE click it never will still happen.
Finally, if you have any antivirus installed in your computer, even double clicking the possibly nasty file your AV will warn you about the risks, and most possibly will detect and put the virus (if any) in quarentine.
About the OP zip file with the PDF what I would say is:
1) You can download any zip you want from anywhere (it won't harm your computer)
2) You can double click the zip file (it won't harm your computer)
3) See what's inside the zip. Some EXE file? Don't double click it. PDF files? Go ahead and enjoy, you're safe.
About me:
a) System Analyst and programmer for almost 30 years
b) Worked for years as a PC technician fixing computers and cleaning systems from viruses and plagues
c) I download myself all sort of shit to my computer and I never (ever) had an infection by something that wasn't an EXE file. Period.
PS: Don't be freak. Be smart. Keep your computer protected by an AV and a Firewall. Don't double click suspicious EXE files.