The mic looks like a rebranded chinese knock-off. There are many on the market and most are quite usable. But without knowing exactly which chinese knock-off it is, you don't have any kind of review or collective experience. Still, I'm sure you can get it to work.
The headphones bother me only because there is a larger probability of variation. Without knowing what they are, you don't know what you're getting. Sound could go from flat (which is what you want) to hyped bass (which is what you don't want). A good test would be if you play music from your iphone on them and they sound awesome, then they are not what you want for recording. I won't go into the headphones vs monitors debate.
I think as a starting point, it will work. If you bought the items separately, you spend maybe 20% more... but you would have more control over what you're buying. A starting point, because as you get more into recording, you will realize where you need to improve and you will be buying more things. Slippery slope and all that.
I have the 2i2 and it sounds good. The only thing about it I don't like is it doesn't have a "blend" knob for balancing playback with recorded channels. The workaround for that is to adjust playback level in software.